CSENG Chemistry
College of Science & Engineering
Twin Cities
Project Title: 
Copper Oxygen Intermediates and New Catalysts for Renewable Polymer Synthesis

Current research in the Tolman group encompasses synthetic bioinorganic and organometallic/polymer chemistry. In the bioinorganic area, the group's objective is to gain a fundamental structural, spectroscopic, and mechanistic understanding of metalloprotein active sites of biological and environmental importance via the synthesis, characterization, and examination of the reactivity of model complexes. The current goal of research in the organometallic/polymer area is to synthesize and characterize a variety of metal complexes for use as catalysts for the polymerization of cyclic esters and for converting biomass feedstocks to useful monomers. In this project, particular emphasis is being placed on developing controlled synthesis of polymers derived from renewable resources.

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